pilipiliÂț»­

 

Stradiotto Research Group

Publications


A = Article; C = Communication/Letter; N = Note; R = Review; H = Highlight; I = Invited

(159) (R,I) "The Development of Cage Phosphine ‘DalPhos’ Ligands to Enable Nickel-Catalyzed Cross-Couplings of (Hetero)aryl Electrophiles." K. M. Morrison and Mark Stradiotto* (Chem. Sci., 2024, 15, 7394-7407). Invited contribution as a Perspective.  

(158) (A) "DalPhos on Demand: Facile Ligand Generation Enables New Ligand Discovery and Expedient Catalyst Screening." J. W. M. MacMillan, R. T. McGuire, A. M. McMahon, T. S. Anderson, K. N. Robertson, and Mark Stradiotto* (ACS Catal., 2024, 14, 566-573).

(157) (C) "Thermal Nickel-Catalyzed N‑Arylation of NH-Sulfoximines with (Hetero)aryl Chlorides Enabled by PhPAd-DalPhos Ligation." S. A. Fisher, C. M. Simon, P. L. Fox, M. J. Cotnam, P. L. DeRoy, and Mark Stradiotto* (Org. Lett., 2024, 26, 1326-1331).

(156) (A) "Ligand-Enabled Nickel Catalysis for the O‑Arylation of Alcohols and Phenols with (Hetero)aryl Chlorides Using a Soluble Organic Base." K. M. Morrison, N. E. BodĂ©, S. M. E. Knight, J. Choi, and Mark Stradiotto* (ACS Catal., 2024, 14, 566-573).

(155) (A,I) "Nickel-Catalyzed O-Arylation of Primary or Secondary Aliphatic Alcohols with (Hetero)aryl Chlorides: A Comparison of Ni(I) and Ni(II) Pre-catalysts." K. M. Morrison, N. J. Roberts, S. L. Dudra, J. P. Tassone, M. J. Ferguson, E. R. Johnson,* and Mark Stradiotto* (J. Org. Chem., 2024, 89, XXXX-XXXX, in press). Invited contribution to Special Issue: Next-Generation Cross-Coupling Chemistry.

(154) (C) "DalPhos/Nickel-Catalyzed C2−H Arylation of 1,3-Azoles Using a Dual-Base System." N. E. BodĂ© and Mark Stradiotto* (Org. Lett., 2023, 25, 8809-8813).

(153) (A) "Probing the Impact of Added Al(OTf)3 on DalPhos/NickelCatalyzed N-Arylations of Amides with (Hetero)aryl Chlorides." M. J. Cotnam, N. Martinek, and Mark Stradiotto* (Eur. J. Org. Chem., 2023, e202301004).

(152) (R) "Advances in Nickel-Catalyzed O-Arylation of Aliphatic Alcohols and Phenols with (Hetero)aryl Electrophiles." K. M. Morrison and Mark Stradiotto* (Synthesis, 2024, 56, 229-238).

(151) (A) "Palladium-Catalyzed Chemoselective Mono-a-Arylation of O-Protected Hydroxyacetone: Efficient Access to a High-Value Synthetic Intermediate." J. W. M. MacMillan, T. Lundrigan, G. Volpin, S. J. Kaldas, P. Holstein, M. J. Ford, N. Guimond,* and Mark Stradiotto* (Adv. Synth. Catal., 2023, 365, 2594-2600).

(150) (A) "Nickel-Catalyzed Chemoselective Arylation of Amino Alcohols." K. M. Morrison, C. S. Yeung, and Mark Stradiotto* (Angew. Chem. Int. Ed. 2023, e202300686). For an article highlighting synthetic utility, see: Org. Process Res. Dev. 2023, 27, 1210–1219.

(149) (A,I) "Nickel-Catalyzed N-Arylation of Optically Pure Amino Acid Esters with Activated (Hetero)aryl Electrophiles." T. Lundrigan, J. P. Tassone, and Mark Stradiotto* (Can. J. Chem., 2023, 121, 275-283). Invited contribution as an Award Lecture submission, Rio Tinto Award, Canadian Society for Chemistry.

(148) (A) "Nickel-Catalyzed N-Arylation of Sulfinamides: A Comparative Study versus Analogous Sulfonamide Cross-Couplings." C. M. Simon, K. N. Robertson, P. L. DeRoy, A. A. Yadav, E. R. Johnson,* and Mark Stradiotto* (Organometallics, 2023, 42, 1704-1710). Invited contribution to Joint Special Issue: Advances and Applications in Catalysis with Earth-Abundant Metals.

(147) (C) "Bisphosphine/Nickel-Catalyzed C-O Cross-Coupling of Phenols with Chloropyridine and Related Electrophiles." N. E. Bodé, R. T. McGuire, and Mark Stradiotto* (Org. Lett., 2022, 24, 8986-8989).

(146) (A) "Comparative Screening of DalPhos/Ni Catalysts in C-N Cross-couplings of (Hetero)aryl Chlorides Enables Development of Aminopyrazole Cross-couplings with Amine Base." N. Martinek, K. M. Morrison, J. M. Field, S. A. Fisher, and Mark Stradiotto* (Chem. Eur. J., 2022, 29, e202203394).

(145) (N) "Nickel-Catalyzed C-N Cross-Coupling of 4-Chloro-1,8-naphthalimides and Bulky, Primary Alkylamines at Room Temperature." J. P. Tassone, T. Lundrigan, T. D. Ashton, and Mark Stradiotto* (J. Org. Chem., 2022, 87, 6492-6498).

(144) (C) "Organic Base Enabled Nickel-Catalyzed Mono-a-Arylation of Feedstock Solvents." J. W. M. MacMillan, R. T. McGuire, and Mark Stradiotto* (Chem. Eur. J., 2022, 28, e202200764).

(143) (A) "Mapping ‘Dual-Base’-Enabled Ni-Catalyzed Aryl Amidations: Application in the Synthesis of 4-Quinolones." R. T. McGuire, T. Lundrigan, J. W. M. MacMillan, K. N. Robertson, A. A. Yadav, and Mark Stradiotto* (Angew. Chem. Int. Ed., 2022, 61, e202200352). Highlighted as a Hot Paper by the journal editors.

(142) (C) "Identification of a Nitrenoid Reductive Elimination Pathway in Nickel-Catalyzed C-N Cross-Coupling" C. M. Simon, S. L. Dudra, R. T. McGuire, M. J. Ferguson, Erin R. Johnson, and Mark Stradiotto* (ACS Catal., 2022, 12, 1475-1480).

(141) (C) "CgPhen-DalPhos Enables the Nickel-Catalyzed O-Arylation of Tertiary Alcohols with (Hetero)Aryl Electrophiles" K. M. Morrison, R. T. McGuire, M. J. Ferguson, and Mark Stradiotto* (ACS Catal., 2021, 11, 10878-10884).

(140) (A) "Structural and Reactivity Comparisons of JosiPhos CyPF-Cy and a Simplified Variant (“CyPBn-Cy”) in Nickel-Catalyzed C(sp2)-N Cross-Couplings." N. E. BodĂ©, J. P. Tassone, M. J. Ferguson, and Mark Stradiotto* (Organometallics, 2021, 40, 2915−2922).

(139) (C,I) "Nickel-Catalyzed N-Arylation of Amides with (Hetero)aryl Electrophiles using a DBU/NaTFA Dual-Base System." T. Lundrigan, J. P. Tassone, and Mark Stradiotto* (Synlett, 2021, 32, 1665-1669). Invited contribution to the thematic cluster on modern aspects of nickel in catalysis.

(138) (C) "Nickel-Catalyzed N-Arylation of Fluoroalkylamines." R. T. McGuire, A. A. Yadav, and Mark Stradiotto* (Angew. Chem. Int. Ed., 2021, 60, 4080-4084). For an article highlighting the synthetic utility, see: Synfacts 2021, 17(02):0179.

(137) (A) "Chromium N-Phosphinoamidine Ethylene Tri-/Tetramerization Catalysts: Designing a Step Change in 1-Octene Selectivity" T. Ogawa, F. Lindeperg, Mark Stradiotto,* L. Turculet,* and O. L. Sydora* (J. Catal., 2021, 394, 444-450).

(136) (A) "Synthetic Investigations of Low-Coordinate (N-Phosphino-amidinate) Nickel Chemistry: Agostic Alkyl Complexes and Benzene Insertion into Ni-H." C. M. Macaulay, M. Samolia, M. J. Ferguson, O. L. Sydora,* D. H. Ess,* Mark Stradiotto,* and L. Turculet* (Dalton Trans., 2020, 49, 4811–4816).

(135) (C) "Ligand-Enabled Nickel-Catalyzed Cross-Coupling of Primary and Secondary Sulfonamides With (Hetero)aryl Chlorides." R. T. McGuire, C. M. Simon, A. A. Yadav, M. J. Ferguson, and Mark Stradiotto* (Angew. Chem. Int. Ed., 2020, 59, 8952-8956).

(134) (A) "Bulky 1,1’-Ferrocenyl Ligands Featuring Diazaphospholene or Dioxaphosphepine Donor Fragments: Catalytic Screening in Nickel-Catalyzed C-N Cross-Coupling " R. T. McGuire, J. S. K. Clark, A. V. Gatien, M. Y. Shen, M. J. Ferguson, and Mark Stradiotto* (Eur. J. Inorg. Chem., 2019, 4112-4116). Highlighted as a Very Important Paper by the journal editors.

(133) (C) "Nickel-Catalyzed C-N Cross-Coupling of Ammonia, (Hetero)anilines, and Indoles with Activated (Hetero)aryl Chlorides Enabled by Ligand Design" R. T. McGuire, J. F. J. Paffile, Y. Zhou, and Mark Stradiotto* (ACS Catal., 2019, 9, 9292-9297).

(132) (C) "PAd2-DalPhos Enables the Nickel-Catalyzed C-N Cross-Coupling of Primary Heteroarylamines and (Hetero)aryl Chlorides" J. S. K. Clark, M. J. Ferguson, R. McDonald, and Mark Stradiotto* (Angew. Chem. Int. Ed., 2019, 58, 6391-6395).

(131) (C) "PhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines" J. P. Tassone, E. V. England, P. M. MacQueen, M. J. Ferguson, and Mark Stradiotto* (Angew. Chem. Int. Ed., 2019, 58, 2485-2489). For an article highlighting the synthetic utility, see: Org. Process Res. Dev. 2019, 23, 674-682.

(130) (A) "A Comparative Analysis of Hydrosilative Amide Reduction Catalyzed by First-Row Transition Metal (Mn, Fe, Co, and Ni) N-Phosphinoamidinate Complexes" C. M. Macaulay, T. Ogawa, R. McDonald, O. L. Sydora,* Mark Stradiotto,* and L. Turculet* (Dalton Trans., 2019, 48, 9581–9587).

(129) (A) "Examining the Impact of Heteroaryl Variants of PAd-DalPhos on Nickel-Catalyzed C(sp2)-N Cross-Couplings" J. S. K. Clark, R. T. McGuire, C. M. Lavoie, M. J. Ferguson and Mark Stradiotto* (Organometallics, 2019, 38, 167−175).

(128) (A) "Probing the Influence of PAd-DalPhos Ancillary Ligand Structure on Nickel-Catalyzed Ammonia Cross-Coupling" C. M. Lavoie, J. P. Tassone, M. J. Ferguson, Y. Zhou, E. R. Johnson,* and Mark Stradiotto* (Organometallics, 2018, 37, 4015−4023).

(127) (A) "Alkene Isomerization-Hydroboration Catalyzed by First-Row Transition Metal (Mn, Fe, Co, and Ni) N-Phosphinoamidinate Complexes: Origin of Reactivity and Selectivity" C. M. Macaulay, S. J. Gustafson, J. T. Fuller III, D.-H. Kwon, T. Ogawa, M. J. Ferguson, R. McDonald, M. D. Lumsden, S. M. Bischof,* O. L. Sydora,* D. H. Ess,* Mark Stradiotto,* and L. Turculet* (ACS Catal., 2018, 8, 9907-9925).

(126) (R,I) "Bisphosphines: A Prominent Ancillary Ligand Class for Application in Nickel-catalyzed C-N Cross-coupling" C. M. Lavoie and Mark Stradiotto* (ACS Catal., 2018, 8, 7228-7250).

(125) (A) "Application of Diazaphospholidine/Diazaphospholene-Based Bisphosphines in Room Temperature Nickel-Catalyzed C(sp2)-N Cross-Couplings of Primary Alkylamines with (Hetero)aryl Chlorides and Bromides" A. V. Gatien, C. M. Lavoie, R. N. Bennett, M. J. Ferguson, R. McDonald, E. R. Johnson, A. W. H. Speed,* and Mark Stradiotto* (ACS Catal., 2018, 8, 5328-5339).

(124) (A,I) "Probing the Effect of Donor-Fragment Substitution in Mor-DalPhos on Palladium-Catalyzed C-N and C-C Cross-coupling Reactivity" S. M. Crawford, C. A. Wheaton, V. Mishra, and Mark Stradiotto* (Can. J. Chem., 2018, 96, 578-586). Issue in honour of Professor Neil Burford.

(123) (C) "Exploiting Ancillary Ligation to Enable Nickel-Catalyzed C-O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols" P. M. MacQueen, J. P. Tassone, C. Diaz, and Mark Stradiotto* (J. Am. Chem. Soc., 2018, 140, 5023-5027). For an article highlighting the synthetic utility, see: Org. Process Res. Dev. 2018, 22, 657-666.

(122) (A,I) "Developing Backbone-Modified Mor-DalPhos Ligand Variants for use in Palladium-Catalyzed C-N and C-C Cross-coupling" M. A. MacLean, C. A. Wheaton, and Mark Stradiotto* (Can. J. Chem., 2018, 96, 712-721). Issue in honour of the 200th anniversary of pilipiliÂț»­.

(121) (C) "(DPEPhos)Ni(mesityl)Br: An Air-Stable Pre-Catalyst for Challenging Suzuki-Miyaura Cross-couplings Leading to Unsymmetrical Biheteroaryls" R. S. Sawatzky and Mark Stradiotto* (Synlett, 2018, 29, 799-804). Highlighted in the ‘News’ section of Synform.

(120) (C) "A Manganese Pre-Catalyst for the Mild Reduction of Amides, Ketones, Aldehydes, and Esters" C. M. Kelly, R. McDonald, O. L. Sydora,* Mark Stradiotto* and L. Turculet* (Angew. Chem. Int. Ed., 2017, 56, 15901-15904).

(119) (A) "Sequential One-pot Three-step Synthesis of Polysubstituted 4-(5-(trifluoromethyl)-1H-pyrazol-4-yl)-1H-1,2,3-triazole Systems" H. G. Bonacorso,* G. M. Dal Forno, C. Wiethan, A. Ketzer, N. Zanatta, C. P. Frizzo, M. A. P. Martins, and Mark Stradiotto (RSC Adv., 2017, 7, 43957-43964).

(118) (A) "Bisphosphine-Ligated Nickel Pre-catalysts in C(sp2)-N Cross-Couplings of Aryl Chlorides: A Comparison of Ni(I) and Ni(II)" C. M. Lavoie, R. McDonald, E. R. Johnson* and Mark Stradiotto* (Adv. Synth. Catal., 2017, 359, 2972-2980).

(117) (A) "Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature" J. P. Tassone, P. M. MacQueen, C. M. Lavoie, M. J. Ferguson, R. McDonald and Mark Stradiotto* (ACS Catal., 2017, 7, 6048-6059).

(116) (A) "Exploring the Influence of Phosphine Ligation on the Gold-Catalyzed Hydrohydrazination of Terminal Alkynes at Room Temperature" N. L. Rotta-Loria, A. J. Chisholm, P. M. MacQueen, R. McDonald, M. J. Ferguson and Mark Stradiotto* (Organometallics, 2017, 36, 2470-2475).

(115) (C) "Nickel-Catalyzed Cross-coupling of Ammonia or Primary Alkylamines with (Hetero)aryl Sulfamates, Carbamates, or Pivalates" P. M. MacQueen and Mark Stradiotto* (Synlett, 2017, 28, 1652-1656).

(114) (A) "Ni and Cu-Catalyzed One Pot Synthesis of Unsymmetrical 1,3-Di(hetero)aryl-1H-indazoles from Hydrazine, o-Chloro(hetero)benzophenones, and (Hetero)aryl Bromides" C. Wiethan, C. M. Lavoie, A. Borzenko, J. S. K. Clark, H. G. Bonacorso* and Mark Stradiotto* (Org. Biomol. Chem. 2017, 15, 5062-5069).

(113) (C,I) " Efficient Cross-Coupling of Secondary Amines/Azoles and Activated (Hetero)Aryl Chlorides Using an Air-Stable DPEPhos/Nickel Pre-Catalyst" R. S. Sawatzky, M. J. Ferguson and Mark Stradiotto* (Synlett, 2017, 28, 1586-1591). Invited follow-up contribution regarding Thieme Chemistry journals award.

(112) (C) "Dehydrogenative B-H/C(sp3)-H Benzylic Borylation Within the Coordination Sphere of Platinum(II)" C. M. Kelly, J. T. Fuller, III, C. M. Macaulay, R. McDonald, M. J. Ferguson, S. M. Bischof, O. L. Sydora,* D. H. Ess,* Mark Stradiotto* and L. Turculet* (Angew. Chem. Int. Ed., 2017, 56, 6312-6316).

(111) (A) "Evaluating 1,1’-Bisphosphinoferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C-N Cross-Coupling of (Hetero)aryl Chlorides" J. S. K. Clark, C. N. Voth, M. J. Ferguson and Mark Stradiotto* (Organometallics 2017, 36, 679-686). Highlighted as an ACS Editors Choice.

(110) (A) "Cobalt- and Iron-Catalyzed Isomerization-Hydroboration of Branched Alkenes: Terminal Hydroboration with Pinacolborane and 1,3,2-Diazaborolanes" T. Ogawa, A. R. Ruddy, O. L. Sydora,* L. Turculet* and Mark Stradiotto* (Organometallics 2017, 36, 417-423). For an article highlighting the synthetic utility, see: Synfacts 2017, 13, 299.

(109) (C) "Nickel-Catalyzed N-Arylation of Primary Amides and Lactams with Activated (Hetero)aryl Electrophiles" C. M. Lavoie, P. M. MacQueen, and Mark Stradiotto* (Chem. Eur. J., 2016, 22, 18752-18755) For an article highlighting the synthetic utility, see: Org. Process Res. Dev. 2017, 21, 142−152.

(108) (A) "A Comparative Reactivity Survey of Some Prominent Bisphosphine Nickel(II) Pre-Catalysts in C-N Cross-Coupling" J. S. K. Clark, C. M. Lavoie, P. M. MacQueen, M. J. Ferguson and Mark Stradiotto* (Organometallics 2016, 35, 3248-3254).

(107) (A) "Synthesis of Pyrazolo[1,5-a]quinoxalin-4(5H)-ones via One-pot Amidation/N–Arylation Reactions Under Transition Metal-Free Conditions" C. Wiethan, S. Z. Franceschini, H. G. Bonacorso* and Mark Stradiotto* (Org. Biomol. Chem. 2016, 14, 8721-8727).

(106) (A) "A Comparative Ancillary Ligand Survey in Palladium-Catalyzed C–O Cross-Coupling of Primary and Secondary Aliphatic Alcohols" R. S. Sawatzky, B. K. V. Hargreaves and Mark Stradiotto* (Eur. J. Org. Chem. 2016, 2444-2449).

(105) (C) "Challenging Nickel-Catalyzed Amine Arylations Enabled by Tailored Ancillary Ligand Design" C. M. Lavoie, P. M. MacQueen, N. L. Rotta-Loria, R. S. Sawatzky, A. Borzenko, A. J. Chisholm, B. K. V. Hargreaves, R. McDonald, M. J. Ferguson and Mark Stradiotto* (Nature Comm. 2016, 7:11073 doi: 10.1038/ncomms11073).

(104) (A) "Synthesis of Tetra-substituted 5-TriïŹ‚uoromethylpyrazoles via Sequential Halogenation/Palladium-Catalyzed C-C and C-N Cross-Coupling" C. Wiethan, W. C. Rosa, H. G. Bonacorso* and Mark Stradiotto* (Org. Biomol. Chem. 2016, 14, 2352-2359).

(103) (C) "Diversification of Edaravone via Palladium-Catalyzed Hydrazine Cross-Coupling: Applications Against Protein Misfolding and Oligomerization of Beta-Amyloid" M. A. MacLean, E. Diez-Cecilia, C. B. Lavery, M. A. Reed, Y. Wang, D. F. Weaver* and Mark Stradiotto* (Bioorg. Med. Chem. Lett., 2016, 26, 100-104).

(102) (C) "Synthesis and Reactivity of a Neutral, Three-Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation" C. M. Kelly, D.-H. Kwon, M. J. Ferguson, S. M. Bischof, O. L. Sydora,* D. H. Ess,* Mark Stradiotto* and L. Turculet* (Angew. Chem. Int. Ed., 2015, 54, 14498-14502).

(101) (C) "Palladium-Catalyzed Mono-alpha-arylation of Acetone at Room Temperature" P. M. MacQueen, A. J. Chisholm, B. K. V. Hargreaves and Mark Stradiotto* (Chem. Eur. J., 2015, 21, 11006-11009).

(100) (C) "Nickel-Catalyzed Monoarylation of Ammonia" A. Borzenko, N. L. Rotta-Loria, P. M. MacQueen, C. M. Lavoie, R. McDonald and Mark Stradiotto* (Angew. Chem. Int. Ed., 2015, 54, 3773-3777). This publication was featured as a Science Concentrate in Chemical and Engineering News 2015, 93(9), 24-25. Named one of the "Top Research Advances in 2015" by Chemical and Engineering News.

(99) (A) "Sulfur-Containing DalPhos Ligand Variants: Synthesis and Application in Buchwald-Hartwig Amination" E. W. F. Cook, C. B. Lavery, C. A. Wheaton, R. McDonald and Mark Stradiotto* (Can. J. Chem., 2015, 93, 326-333).

(98) (A) "Utilizing Mor-DalPhos/Palladium-Catalyzed Monoarylation in the Multicomponent One-Pot Synthesis of Indoles" N. L. Rotta-Loria, A. Borzenko, P. G. Alsabeh, C. B. Lavery and Mark Stradiotto* (Adv. Synth. Catal., 2015, 357, 100-106).

(97) (C) "(N-Phosphinoamidinate)Cobalt-Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity" A. J. Ruddy, O. L. Sydora,* B. L. Small, Mark Stradiotto* and L. Turculet* (Chem. Eur. J., 2014, 20, 13918-13922).

(96) (A) "Synthesis, Structural Characterization, and Reactivity of Cp*Ru(N-phosphinoamidinate) Complexes" C. M. Kelly, A. J. Ruddy, C. A. Wheaton, O. L. Sydora,* B. L. Small, Mark Stradiotto,* and L. Turculet* (Can. J. Chem., 2014, 92, 194-200).

(95) (A) "Organic and Organometallic Derivatives of Pentaphenylbenzene, C6Ph5X: Correlation of Peripheral Phenyl Ring Orientations with the Steric Bulk of ‘X’" S. Brydges, B. Gildea, J. P. Grealis, H. Muller-Bunz, Mark Stradiotto, M. Casey, M. J. McGlinchey* (Can. J. Chem., 2013, 91, 1098-1111).

(94) (A) "New Phosphine-Functionalized NHC Ligands: Discovery of an Effective Catalyst for the Room Temperature Amination of Aryl Chlorides with Primary and Secondary Amines" C. A. Wheaton, J.-P. J. Bow, and Mark Stradiotto* (Organometallics, 2013, 32, 6148−6161). “Strem Chemicals Award for Pure or Applied Inorganic Chemistry” contribution.

(93) (A) "(N-Phosphinoamidinate)Iron Pre-Catalysts for the Room Temperature Hydrosilylation of Carbonyl Compounds with Broad Substrate Scope at Low Loadings" A. J. Ruddy, C. M. Kelly, S. M. Crawford, C. A. Wheaton, O. L. Sydora,* B. L. Small, Mark Stradiotto,* and L. Turculet* (Organometallics, 2013, 32, 5581-5588). This publication was featured as a Science Concentrate in Chemical and Engineering News 2013, 91(42), 29.

(92) (A) "BippyPhos: A Single Ligand With Unprecedented Scope in the Buchwald-Hartwig Amination of (Hetero)aryl Chlorides." S. M. Crawford, C. B. Lavery and Mark Stradiotto* (Chem. Eur. J., 2013, 19, 16760-16771).

(91) (A) "Palladium-catalyzed Carbonylative a-Arylation of Acetone and Acetophenones to 1,3-Diketones." J. Schranck, A. Tlili, P. G. Alsabeh, H. Neumann, Mark Stradiotto* and M. Beller* (Chem. Eur. J., 2013, 19, 12624-12628).

(90) (A) "Probing the Utility of Palladium Complexes Supported by Morpholine-Functionalized NHC Ligands in Buchwald-Hartwig Amination." C. A. Wheaton and Mark Stradiotto* (Can. J. Chem., 2013, 91, 755-762).

(89) (C) "Addressing Challenges in Palladium-Catalyzed Cross-Couplings of Aryl Mesylates: Monoarylation of Ketones and Primary Alkyl Amines." P. G. Alsabeh and Mark Stradiotto* (Angew. Chem. Int. Ed., 2013, 52, 7242 –7246).

(88) (A) "Pd2dba3/Bippyphos: A Robust Catalyst System for the Hydroxylation of Aryl Halides with Broad Substrate Scope." C. B. Lavery, N. L. Rotta-Loria, R. McDonald, and Mark Stradiotto* (Adv. Synth. Catal., 2013, 355, 981-987).

(87) (A) "An Examination of the Palladium/Mor-DalPhos Catalyst System in the Context of Selective Ammonia Monoarylation at Room Temperature." P. G. Alsabeh, R. J. Lundgren, R. McDonald, C. C. C. Johansson Seechurn, T. J. Colacot, and Mark Stradiotto* (Chem. Eur. J., 2013, 19, 2131-2141).

(86) (C) "A Selective Palladium-catalyzed Carbonylative Arylation of Aryl Ketones to Vinylbenzoates." J. Schranck, A. Tlili, H. Neumann, P. G. Alsabeh, Mark Stradiotto, M. Beller* (Chem. Eur. J., 2012, 18, 15592-15597).

(85) (A) "Aminocarbonylation of (Hetero)aryl Bromides with Ammonia and Amines using a Palladium/DalPhos Catalyst System." P. G. Alsabeh, Mark Stradiotto,* H. Neumann, M. Beller* (Adv. Synth. Catal., 2012, 354, 3065-3070).

(84) (A) "Palladium-Catalyzed Mono-α-arylation of Carbonyl-Containing Compounds with Aryl Halides using DalPhos Ligands." S. M. Crawford, P. G. Alsabeh, Mark Stradiotto* (Eur. J. Org. Chem., 2012, 6042-6050).

(83) (R,I) " Exploiting the Mor-DalPhos Ancillary Ligand in Challenging Palladium-Catalysed Monoarylation Reactions." Mark Stradiotto* (Chimica Oggi/Chemistry Today, 2012, 30, 64-67).

(82) (R,I) "Recent Advances in Buchwald-Hartwig Amination Enabled by the Application of Sterically Demanding Phosphine Ancillary Ligands." R. J. Lundgren and Mark Stradiotto* (Aldrichimica Acta, 2012, 45, 59-65).

(81) (R,I) "[4-[2-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino-ÎșP]phenyl]morpholine]chlorogold." Mark Stradiotto* (electronic-Encyclopedia of Reagents for Organic Synthesis (e-EROS), 2012).

(80) (R,I) "Addressing Challenges in Palladium-Catalyzed Cross-Coupling Reactions Through Ligand Design." R. J. Lundgren and Mark Stradiotto* (Chem. Eur. J., 2012, 18, 9758-9769).

(79) (C) "Efficient Palladium-Catalyzed Synthesis of Substituted Indoles Employing a New (Silanyloxyphenyl)phosphine Ligand." C. B. Lavery, R. McDonald, and Mark Stradiotto* (Chem. Commun., 2012, 48, 7277-7279).

(78) (A) "Buchwald–Hartwig Amination of (Hetero)aryl Chlorides by Employing Mor-DalPhos under Aqueous and Solvent-Free Conditions." B. J. Tardiff and Mark Stradiotto* (Eur. J. Org. Chem., 2012, 3972-3977).

(77) (A) "Can a Formally Zwitterionic Rhodium(I) Complex Emulate the Charge Density of a Cationic Rhodium(I) Complex? A Combined Synchrotron X-ray and Theoretical Charge-Density Study." E.-E. Bendeif, C. F. Matta,* Mark Stradiotto,* P. Fertey, and C. Lecomte* (Inorg. Chem., 2012, 51, 3754−3769).

(76) (C,I) "Generation of [(IPr)Pd(PR2Cl)] Complexes via P-Cl Reductive Elimination." B. J. Tardiff, K. D. Hesp, M. J. Ferguson, and Mark Stradiotto* (Dalton Trans., 2012, 41, 7883–7885; invited contribution to the “Dalton Transactions New Talent Americas Issue”). Identified as a ‘Hot Paper’ by the journal editors.

(75) (A) "Stoichiometric Reactivity Relevant to the Mor-DalPhos/Pd Catalyzed Cross-Coupling of Ammonia and 1‑Bromo-2-(phenylethynyl)benzene." P. G. Alsabeh, R. McDonald, and Mark Stradiotto* (Organometallics, 2012, 31, 1049-1054).

(74) (A) "Rational and Predictable Chemoselective Synthesis of Oligoamines via Buchwald-Hartwig Amination of (Hetero)Aryl Chlorides Employing Mor-DalPhos." B. J. Tardiff, R. McDonald, M. J. Ferguson, and Mark Stradiotto* (J. Org. Chem., 2012, 77, 1056-1071).

(73) (R,I) "Design of New P,N "DalPhos" Ligands: Applications in Transition Metal Catalysis." R. J. Lundgren, K. D. Hesp, and Mark Stradiotto* (Synlett, 2011, 2443-2458).

(72) (C) "Palladium-Catalyzed Synthesis of Indoles via Ammonia Cross-Coupling-Alkyne Cyclization." P. G. Alsabeh, R. J. Lundgren, L. E. Longobardi, and Mark Stradiotto* (Chem. Commun., 2011, 47, 6936-6938).

(71) (C) "Palladium-Catalyzed Mono-a-Arylation of Acetone with Aryl Halides and Tosylates." K. D. Hesp, R. J. Lundgren, and Mark Stradiotto* (J. Am. Chem. Soc., 2011, 133, 5194-5197).

(70) (A) "Probing Mesitylborane and Mesitylborate Ligation Within the Coordination Sphere of Cp*Ru(PiPr3)+: A Combined Synthetic, X-Ray Crystallographic, and Computational Study." K. D. Hesp, F. O. Kannemann, M. A. Rankin, R. McDonald, M. J. Ferguson, and Mark Stradiotto* (Inorg. Chem., 2011, 50, 2431-2444).

(69) (C) "Stereo- and Regioselective Gold-Catalyzed Hydroamination of Internal Alkynes with Dialkylamines." K. D. Hesp and Mark Stradiotto* (J. Am. Chem. Soc., 2010, 132, 18026-18029).

(68) (N) "Platinum-Catalyzed Alkene Cyclohydroamination: Evaluating the Utility of Bidentate P,N/P,P Ligation and Phosphine-Free Catalyst Systems." C. B. Lavery, M. J. Ferguson, and Mark Stradiotto* (Organometallics, 2010, 29, 6125-6128).

(67) (C) "Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Tosylates with Hydrazine." R. J. Lundgren and Mark Stradiotto* (Angew. Chem. Int. Ed., 2010, 49, 8686-8690). This publication was featured as an Article in Chemical and Engineering News 2010, 88(42), 8.

(66) (H) " Transition Metal-Catalyzed Trifluoromethylation of Aryl Halides." R. J. Lundgren and Mark Stradiotto* (Angew. Chem. Int. Ed., 2010, 49, 9322-9324).

(65) (R,I) "Rhodium- and Iridium-Catalyzed Hydroamination of Alkenes." K. D. Hesp and Mark Stradiotto* (ChemCatChem, 2010, 2, 1192-1207).

(64) (N,I) "Rhodium Phosphino-enolate Complexes as Chemo- and Regioselective Catalysts for the Hydroformylation of Styrenes." Y.-S. Uh, A. Boyd, V. R. Little, P. G. Jessop,* K. D. Hesp, J. Cipot-Wechsler and Mark Stradiotto* (J. Organomet. Chem., 2010, 695, 1869-1872; invited contribution to the thematic issue “Catalytic addition of E-H bonds to non-activated carbon-carbon multiple bonds”).

(63) (C) "A P,N-Ligand for Pd-Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Arylations, and Room Temperature Reactions." R. J. Lundgren, B. D. Peters, P. G. Alsabeh, and Mark Stradiotto* (Angew. Chem. Int. Ed., 2010, 49, 4071-4074). This publication was featured as a Science Concentrate in Chemical and Engineering News 2010, 88(21), 32.

(62) (A,I) "Intramolecular Hydroamination of Unactivated Alkenes with Secondary Alkylamines Catalyzed by Iridium Phosphino-phenolate Complexes." K. D. Hesp, R. McDonald, and Mark Stradiotto* (Can. J. Chem., 2010, 88, 700-708; invited contribution to issue in honour of Russell Boyd).

(61) (A) "A Highly Versatile Catalyst System for the Cross-Coupling of Aryl Chlorides and Amines." R. J. Lundgren, A. Sappong-Kumankumah, and Mark Stradiotto*. (Chem. Eur. J., 2010, 16, 1983-1991). This publication was featured as a Science Concentrate in Chemical and Engineering News 2010, 88(21), 32.

(60) (A) "[Ir(COD)Cl]2 as a Catalyst Precursor for the Intramolecular Hydroamination of Unactivated Alkenes with Primary Amines and Secondary Alkyl- or Arylamines: A Combined Catalytic, Mechanistic and Computational Investigation." K. D. Hesp, S. Tobisch, and Mark Stradiotto* (J. Am. Chem. Soc., 2010, 132, 413-426).

(59) (R) "Zwitterionic Relatives of Cationic Platinum Group Metal Complexes: Applications in Stoichiometric and Catalytic s-Bond Activation." Mark Stradiotto*, K. D. Hesp, and R. J. Lundgren. (Angew. Chem. Int. Ed., 2010, 49, 494-512).

(58) (A) "Exploring the Reactivity of a Coordinatively Unsaturated Cp*Ru(k2-P,O) Complex with Small Molecule Substrates: Application in E-H Bond Activation (E = H, B, and Si)." M. A. Rankin, K. D. Hesp, G. Schatte, R. McDonald, and Mark Stradiotto*. (Dalton Trans., 2009, 4756-4765).

(57) (N) "Synthesis, Characterization, and Catalytic Application of a New Chiral P,N-Indene Ligand Derived from (R)-BINOL." D. Wechsler, G. Schatte, and Mark Stradiotto*. (J. Organomet. Chem., 2009, 694, 1943-1947).

(56) (C) "Intramolecular Hydroamination of Unactivated Alkenes with Secondary Alkyl- and Arylamines Employing [Ir(COD)Cl]2 as a Catalyst Precursor." K. D. Hesp and Mark Stradiotto*. (Org. Lett., 2009, 11, 1449-1452).

(55) (A, I) "Exploring the Utility of a New Chiral Phosphoramidite P,N-Ligand Derived from (R)-BINOL and 7-Azaindole in Asymmetric Catalysis." D. Wechsler and Mark Stradiotto*. (Can. J. Chem., 2009, 87, 72-79; issue in honour of Richard Puddephatt).

(54) (A) "Probing the Dynamics and Reactivity of a Stereochemically Non-Rigid Cp*Ru(H)(k2-P,Carbene) Complex." M. A. Rankin, D. F. MacLean, R. McDonald, M. J. Ferguson, M. D. Lumsden, and Mark Stradiotto*. (Organometallics, 2009, 28, 74-83).

(53) (A) "Indenyl Hemilability: Unveiling a Masked (h5-C5Me5)Ru(k2-P,Carbene) Zwitterion Via Facile and Reversible Ru-C(sp3) Bond Cleavage." M. A. Rankin, G. Schatte, R. McDonald, and Mark Stradiotto*. (Organometallics, 2008, 27, 6286-6299).

(52) (A) "New Cationic and Zwitterionic Cp*M(k2-P,S) Complexes (M = Rh, Ir): Divergent Reactivity Pathways Arising from Alternative Modes of Ancillary Ligand Participation in Substrate Activation." K. D. Hesp, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (J. Am. Chem. Soc., 2008, 130, 16394-16406).

(51) (C) "(k2-P,S)Pt(benzyl) Complexes Derived from 1/3-PiPr2-2-StBu-Indene: Facile Synthesis of Carbanion- and Borate-Containing Zwitterions." K. D. Hesp, R. McDonald, M. J. Ferguson, G. Schatte, and Mark Stradiotto*. (Chem. Commun., 2008, 5645-5647).

(50) (A) "Rapid Ketone Transfer Hydrogenation Employing Simple, In Situ Prepared Iridium(I) Pre-catalysts Supported by ‘Non N-H’ P,N-Ligands." R. J. Lundgren and Mark Stradiotto*. (Chem. Eur. J., 2008, 14, 10388-10395).

(49) (C) "Synthesis and Characterization of a Cationic Ruthenium Complex Featuring an Unusual Bis(h2-B-H) Monoborane Ligand." K. D. Hesp, M. A. Rankin, R. McDonald, and Mark Stradiotto*. (Inorg. Chem., 2008, 47, 7471-7473).

(48) (A) "Neutral, Cationic, and Zwitterionic Ru(II) Atom Transfer Radical Addition Catalysts Supported by P,N-Substituted Indene or Indenide Ligands." R. J. Lundgren, M. A. Rankin, R. McDonald, and Mark Stradiotto*. (Organometallics, 2008, 27, 254-258).

(47) (C) "Reactivity of a Coordinatively Unsaturated Cp*Ru(k2-P,O) Complex." M. A. Rankin, K. D. Hesp, G. Schatte, R. McDonald, and Mark Stradiotto*. (Chem. Commun., 2008, 250-252).

(46) (A) "Silylene Extrusion from Organosilanes via Double Geminal Si-H Bond Activation by a Cp*Ru(k2-P,N)+ Complex: Observation of a Key Stoichiometric Step in the Glaser-Tilley Alkene Hydrosilylation Mechanism." M. A. Rankin, D. F. MacLean, G. Schatte, R. McDonald, and Mark Stradiotto*. (J. Am. Chem. Soc., 2007, 129, 15855-15864).

(45) (A) "New Racemic Planar-Chiral Metalloligands Derived from Donor-Substituted Indenes: A Synthetic, Structural, and Catalytic Investigation." D. Wechsler, M. A. Rankin, R. McDonald, M. J. Ferguson, G. Schatte, and Mark Stradiotto*. (Organometallics, 2007, 26, 6418-6427).

(44) (A) "Exploring the Utility of Neutral Rhodium and Iridium k2-P,O and k2-P(S),O Complexes as Catalysts for Alkene Hydrogenation and Hydrosilylation." K. D. Hesp, D. Wechsler, J. Cipot, A. Myers, R. McDonald, M. J. Ferguson, G. Schatte, and Mark Stradiotto*. (Organometallics, 2007, 26, 5430-5437).

(43) (C) "Remarkably Facile and Reversible Ru-C(sp3) Bond Cleavage to Give a Reactive 16-Electron Cp*Ru(k2-P,Carbene) Zwitterion." M. A. Rankin, G. Schatte, R. McDonald, and Mark Stradiotto*. (J. Am. Chem. Soc., 2007, 129, 6390-6391).

(42) (C) "A Remarkably Active, Formally Zwitterionic Ru Catalyst Precursor for the Transfer Hydrogenation of Ketones that Does Not Feature an Ancillary Ligand N-H Functionality." R. J. Lundgren, M. A. Rankin, R. McDonald, G. Schatte, and Mark Stradiotto*. (Angew. Chem. Int. Ed., 2007, 46, 4732-4735). Identified as a ‘Hot Paper’ by the journal editors.

(41) (A) "Au(I) Complexes Supported by Donor-Functionalized Indene Ligands: Synthesis, Characterization, and Catalytic Behavior in Aldehyde Hydrosilylation." B. M. Wile, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Organometallics, 2007, 26, 1069-1076).

(40) (A) "Cationic and Formally Zwitterionic Rh(I) and Ir(I) Derivatives of a P,N-Substituted Indene: A Comparative Synthetic, Structural, and Catalytic Investigation." J. Cipot, R. McDonald, M. J. Ferguson, G. Schatte, and Mark Stradiotto*. (Organometallics, 2007, 26, 594-608).

(39) (N) "Catalytic Alkene Hydroboration Mediated by Cationic and Formally Zwitterionic Rhodium(I) and Iridium(I) Derivatives of a P,N-Substituted Indene." J. Cipot, C. M. Vogels, R. McDonald, S. A. Westcott*, and Mark Stradiotto*. (Organometallics, 2006, 25, 5965-5968).

(38) (C) "Silver-Catalyzed Hydrosilylation of Aldehydes." B. M. Wile and Mark Stradiotto*. (Chem. Commun., 2006, 4104-4106).

(37) (A) "Rh(I) and Ir(I) Derivatives of a P(S),N-Substituted Indene Ligand: Synthetic, Structural, and Catalytic Alkene Hydrosilylation Studies." D. Wechsler, A. Myers, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Inorg. Chem., 2006, 45, 4562-4570).

(36) (A) "Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity" P. Sangtrirutnugul, Mark Stradiotto, and T. D. Tilley*. (Organometallics, 2006, 25, 1607-1617).

(35) (A) "Neutral and Cationic Pt(II) Complexes Supported by a P,N-Functionalized Indene Ligand: Structural and Reactivity Comparisons with a Related Au(III) Zwitterion." B. M. Wile, R. J. Burford, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Organometallics, 2006, 25, 1028-1035).

(34) (A, I) "Exploring the Utility of Neutral Rh(I) and Ir(I) k2-(P,O)MCOD Catalyst Complexes for the Addition of Triethylsilane to Styrene." J. Cipot, M. J. Ferguson, and Mark Stradiotto*. (Inorg. Chim. Acta, 2006, 359, 2780-2785; issue in honour of Brian James).

(33) (C) "A Rare Example of Efficient Alkene Hydrogenation Mediated by a Neutral Ir(I) Complex." J. Cipot, R. McDonald, and Mark Stradiotto*. (Organometallics, 2006, 25, 29-31).

(32) (C) "New Bidentate Cationic and Zwitterionic Relatives of Crabtree’s Hydrogenation Catalyst." J. Cipot, R. McDonald, and Mark Stradiotto*. (Chem. Commun., 2005, 4932-4934).

(31) (A) "Exploring the Influence of Ancillary Ligand Charge and Geometry on the Properties of New Coordinatively Unsaturated Cp*(k2-P,N)Ru+ Complexes: Linkage Isomerism, Double C-H Bond Activation, and Reversible a-H Elimination." M. A. Rankin, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Organometallics, 2005, 24, 4981-4994).

(30) (C) "Coordinatively Unsaturated Cationic and Zwitterionic Cp*Ru(k2-P,N) Complexes: Ligand Assisted Double Geminal C-H Bond Activation and Reversible a-H Elimination at Ruthenium." M. A. Rankin, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Angew. Chem. Int. Ed., 2005, 44, 3603-3606).

(29) (A) "Synthesis and Reactivity of New k2-[P,N]Pt(II) Complexes of Diisopropylphosphino-Substituted 2-Dimethylaminoindene." B. M. Wile, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Organometallics, 2005, 24, 1959-1965).

(28) (A) "Synthesis and Crystallographic Characterization of New Mn(I) Complexes of Donor-Functionalized Indenes." J. Cipot, D. Wechsler, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Organometallics, 2005, 24, 1737-1746).

(27) (C) "Structurally Diverse Rh(I) and Mn(I) Complexes Derived from the New Ambidentate Indene Ligand, (1-{iPr2P(S)}-2-{NMe2})C9H6." D. Wechsler, R. McDonald, M. J. Ferguson, and Mark Stradiotto*. (Chem. Commun., 2004, 2446-2447).

(26) (A) "A New Fluorous Soluble Lewis Acidic Borane System." H. Luong, M. E. Eelman, and Mark Stradiotto*. (Can. J. Chem, 2004, 82, 533-538).

(25) (A) "The Divergent Isomerization Behavior and Rh(I) Coordination Chemistry of Indenyl Ligands Bearing Either One or Two Pnictogen Donor Fragments." J. Cipot, D. Wechsler, Mark Stradiotto*, R. McDonald, and M. J. Ferguson. (Organometallics, 2003, 22, 5185-5192).

(24) (C) "A Catalytically Active, Charge-Neutral Rh(I) Zwitterion Featuring a P,N-Substituted “Naked” Indenide Ligand." Mark Stradiotto*, J. Cipot, and R. McDonald. (J. Am. Chem. Soc., 2003, 125, 5618-5619).

(23) (A) "The Synthesis and Structural Characterization of Linear and Macrocyclic Bis(dinitrosyliron) Complexes Supported by Bis(phosphine) Bridging Ligands." L. Li*, N. Reginato, M. Urschey, Mark Stradiotto,* and J. D. Liarakos. (Can. J. Chem, 2003, 81, 468-475).

(22) (R, I) "h1-Indenyl Derivatives of Transition Metal and Main Group Elements: Synthesis, Characterization and Molecular Dynamics." Mark Stradiotto* and M. J. McGlinchey*. (Coord. Chem. Rev., 2001, 219-221, 311-378).

(21) (A, I) "Generation and Reactivity of (i±Ê°ù­2PCH2CH2PiPr2)RhPH(2,4,6-tBu3C6H2). Catalytic Carbon-Phosphorus Bond Formation via Intramolecular C-H/P-H Dehydrogenative Cross-Coupling." Mark Stradiotto, K. L. Fujdala, and T. D. Tilley*. (Helv. Chim. Acta, 2001, 84, 2958-2970; issue in honour of Luigi Venanzi).

(20) (C) "Iridium(III) Complexes of the New Tridentate Bis(8-quinolyl)silyl (“NSiN”) Ligand." Mark Stradiotto, K. L. Fujdala, and T. D. Tilley*. (Chem. Commun., 2001, 1200-1201).

(19) (A) "Diels-Alder Adducts of 5-Alkynylcyclopentadienols with Tetracyanoethylene and Dimethyl Acetylenedicarboxylate: An X-Ray Crystallographic Study of Unexpected Rearrangement Products." J. A. Dunn, Mark Stradiotto, and M. J. McGlinchey*. (J. Org. Chem., 2000, 65, 4861-4863).

(18) (A) "Reactions of C6F5Li with Tetracyclone and 3-Ferrocenyl-2,4,5-Triphenylcyclopentadienone: A 19F NMR and X-Ray Crystallographic Study of Hindered Pentafluorophenyl Rotations." H. K. Gupta, Mark Stradiotto, D. W. Hughes, and M. J. McGlinchey*. (J. Org. Chem., 2000, 65, 3652-3658).

(17) (A) "The Molecular Dynamics and Reactivity of Tris(inden-1-yl)silane: An NMR Spectroscopic and X-Ray Crystallographic Study." Mark Stradiotto, M. A. Brook,* and M. J. McGlinchey*. (J. Chem. Soc., Perkin Trans. 2, 2000, 611-618).

(16) (A) "Crystallographic Characterization of a Stable 7-Phosphanorbornadiene Oxide: 2,3-Benzo-1,4,5,6,7-pentaphenyl-7-phosphabicyclo[2.2.1]hept-5-ene-oxide." C. Gottardo*, S. Fratpietro, A. N. Hughes, and Mark Stradiotto. (Heteroatom Chem., 2000, 11, 182-186).

(15) (A) "Probing the Effect of Organic and Organometallic Functionalization on [1,5]-Silicon Shifts in Indenylsilanes." Mark Stradiotto*, P. Hazendonk, A. D. Bain, M. A. Brook,* and M. J. McGlinchey*. (Organometallics, 2000, 19, 590-601).

(14) (A) "Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-Ray Crystallographic and NMR Study." H. K. Gupta, N. Rampersad, Mark Stradiotto, and M. J. McGlinchey*. (Organometallics, 2000, 19, 184-191).

(13) (A) "The Homo- and Cross-[2+2]-Cycloaddition of 1,1-Diphenylsilene and 1,1-Diphenylgermene. Absolute Rate Constants for Dimerization and the Molecular Structures and Photochemistry of the Resulting 1,3-Dimetallacyclobutanes." N. P. Toltl, Mark Stradiotto, T. L. Morkin, and W. J. Leigh*. (Organometallics, 1999, 18, 5643-5652).

(12) (A) "The Molecular Dynamics and Cycloaddition Chemistry of Tris(1-indenyl)allylsilane: Generation Of The First Crystallographically Characterized Tris(benzonorbornyl)silane." Mark Stradiotto, M. A. Brook, and M. J. McGlinchey*. (New J. Chem., 1999, 317-321).

(11) (N) "Hexacarbonylcobalt-Protected 1,3-Dioxa-2-Silacycloheptynes: Potential Precursors to Strained Heterocyclic Systems." M. A. Brook*, J. Urschey, and Mark Stradiotto. (Organometallics, 1998, 17, 5342-5346).

(10) (A) "A Synthetic and X-Ray Crystallographic Study of the Indenyl-Phosphine Complexes 1,3-(Ph2P=X)2(C9H6), (X = O, S) and (h5-C9H5(Ph2P=S)2)[Mn(CO)3]: Versatile Ligands for the Preparation of Heteropolymetallic Complexes." Mark Stradiotto, C. Kozak, and M. J. McGlinchey*. (J. Organomet. Chem., 1998, 564, 101-108).

(9) (A) "The Electrochemical and IR-Spectroelectrochemical Studies of the Intermediates in the Catalytic Electrocarboxylation of Alkyl Halides with CO2." G. Zheng, Mark Stradiotto, and L. Li*. (J. Electroanal. Chem., 1998, 453, 79-88).

(8) (C, I) "Can Metal Clusters Assist Silicon Migrations? An NMR Spectroscopic and X-Ray Crystallographic Study." Mark Stradiotto, M. A. Brook, and M. J. McGlinchey*. (Inorg. Chem. Commun., 1998, 1, 105-108).

(7) (A) "Synthesis, X-Ray Crystal Structure, High Field NMR and Electrochemical Studies of a Novel Iron Dinitrosyl Complex, Fe(NO)2[P(OMe)3](h2-TCNE)." A. Horsken, G. Zheng, Mark Stradiotto, C. T. C. McCrory, and L. Li*. (J. Organomet. Chem., 1998, 558, 1-9).

(6) (A) "The Diels-Alder Dimerization of Cyclopenta[l]phenanthrene (Dibenz[e,g]indene) with Iso-dibenzindene: A Computational, NMR Spectroscopic, and X-Ray Crystallographic Study."  S. S. Rigby, Mark Stradiotto, S. Brydges, S. Top, A. D. Bain, and M. J. McGlinchey*. (J. Org. Chem., 1998, 63, 3735-3740).

(5) (A) "The Fluxional Character of (h5-C5H5)Fe(CO)2(h1-C9H7): Evidence for the [4+2] Cycloaddition of a Metal-Substituted Isoindene with Tetracyanoethylene." Mark Stradiotto, D. W. Hughes, A. D. Bain, M. A. Brook, and M. J. McGlinchey*. (Organometallics, 1997, 16, 5563-5568).

(4) (A) "Oligoalkynylsilanes: Templates for Inorganometallic Polymers." T. Kuhnen, Mark Stradiotto, R. Ruffolo, M. J. McGlinchey, and M. A. Brook*. (Organometallics, 1997, 16, 5048-5057).

(3) (A) "Using Hydrosilylation to Assemble Organometallic Polymers Containing Combinations of Silicon-Based Functional Groups." T. Kuhnen, R. Ruffolo, Mark Stradiotto, M. J. McGlinchey, and M. A. Brook*. (Organometallics, 1997, 16, 5042-5047).

(2) (C) "The Structure of 1-Styrylsilatrane." Mark Stradiotto*, G. Crowe, R. Ruffolo, and M. A. Brook. (Acta Cryst., 1997, C53, 637-639).

(1) (A) "Multi-Dimensional NMR Study on the Fluxional Behaviour of Tris(indenyl)methylsilane: Molecular Dynamics Mapped Onto a Hypercube." Mark Stradiotto, S. S. Rigby, D. W. Hughes, A. D. Bain, M. A. Brook, and M. J. McGlinchey*. (Organometallics, 1996, 15, 5645-5652).